|
|
(Z)-2-methylbutanal_oxime <=> (2S)-methylbutanenitrile + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-9641
|
|
|
|
N-hydroxy-L-isoleucine + reduced_[NADPH-hemoprotein_reductase] + O2 <=> N,N-dihydroxy-L-isoleucine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-9638
|
|
|
|
(1E,2S)-2-methylbutanal_oxime <=> (Z)-2-methylbutanal_oxime
|
1.14.14.41
(E)-2-methylbutanal oxime monooxygenase
|
–
|
|
BRENDA:
BR51940
KEGG:
R10030
MetaCyc:
RXN-9640
|
|
|
|
H+ + N,N-dihydroxy-L-isoleucine <=> (1E,2S)-2-methylbutanal_oxime + CO2 + H2O
|
1.14.14.38
valine N-monooxygenase
1.14.14.39
isoleucine N-monooxygenase
|
–
–
|
|
BRENDA:
BR49379
KEGG:
R10029
MetaCyc:
RXN-9639
|
|
|
|
(2S)-methylbutanenitrile + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 2-Methyl-2-hydroxybutyronitrile + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
|
MetaCyc:
RXN-9642
|
|
|
|
L-isoleucine + reduced_[NADPH-hemoprotein_reductase] + O2 <=> N-hydroxy-L-isoleucine + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
not assigned
|
–
|
|
MetaCyc:
RXN-9636
|
|
|
|
UDP-glucose + 2-Methyl-2-hydroxybutyronitrile <=> lotaustralin + UDP + H+
|
2.4.1.63
linamarin synthase
|
–
|
|
KEGG:
R10037
MetaCyc:
RXN-9643
|
|